Superelastic titanium alloy has potential for space missions
I was recently disappointed to learn, on looking into its status, of the problems in the industrialization of the FFC Cambridge Process for the electroreduction of titanium oxides to the metal useful for its alloys. Hopefully these will be overcome, since methods to improve production of titanium metal could have a huge positive impact in the world, as bleak as the future seems today.
Thus this news item in Nature caught my eye:
Superelastic titanium alloy has potential for space missions
Subtitle:
Metallurgists have designed an extraordinary titanium alloy that is light, strong and flexible, and which recovers its original shape after large amounts of deformation even when as cold as liquid helium or hotter than boiling water.
From the text:
Nearly all metals can be strengthened, yet it is a struggle to make them stretch or bend flexibly and reversibly like rubber. Why? When a metal is stretched, defects form in its crystal lattice and thereby dissipate the strain energy (the energy stored from applied stress). This limits the amount of deformation that can be recovered (the recoverable strain) to less than 0.5% and causes permanent shape change. Metals are therefore good at permanently retaining their shape and are resistant to breaking, but they are not suitable for applications in which a material cycles through large shape changes. Writing in Nature, Song et al.1 report an impressive lightweight titanium alloy that has high mechanical strength and yet recovers strain of more than 5% across an extensive temperature range with potential applications for biomedical devices, energy infrastructure and space exploration.
In 1932, a seminal discovery2 was made that informed subsequent efforts to make metallic alloys with rubber-like flexibility. This was the discovery of mechanically assisted phase transformation a phenomenon in which the atoms in an alloy move collectively in response to an external mechanical load, reversibly altering the crystal structure. Mechanically assisted phase transformation enables the recovery of an immense amount (several per cent) of strain while producing minimal strain-energy-dissipating defects. Alloys that have this appealing mechanical functionality are said to be superelastic.
Superelasticity is useful for a multitude of uses in which materials must withstand substantial deformation yet return smoothly to their original shape. However, superelasticity often occurs in a narrow temperature range, imposing stringent constraints on the operating conditions of potential applications. For this reason, only a handful of superelastic alloys are currently used...
The alloys, the chief component of which is aluminum were discovered with the assistance of careful thermodynamic modeling.
The full scientific paper, to which the news item refers, and which is open sourced, is here:
Song, Y., Xu, S., Sato, S.
et al. A lightweight shape-memory alloy with superior temperature-fluctuation resistance Nature 638, 965971 (2025).
My son is working on alloys with aluminum content for nuclear applications. It's a little out of the temperature range of his interest, but I'll share it with him for interest.